Thanks for your report.
Quick question, does app starts in your case as expected, but reports invalid startup setting or the app startup after reboot doesn't work at all?
This toggle indicator relies on specific isEnabled
check which is OS dependent.
In some cases startup might work properly after it was enabled, even if the indicator says otherwise. In such case in order to disable the startup user would have to reenable it and then immediately disable it.
... but it would be good to know if app startup works for you by any chance?
Is that the Flatpak or AppImage release? (edited)